ANM
2010
3rd
International Conference on Advanced Nano Materials
12-15 September 2010 - Agadir, Morocco
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Abstract
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ANMM227 |
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METAL OXIDE NANOWIRES FOR SENSORS AND SOLAR CELLS |
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C. Baratto, A. Braga, E.
Comini, S. Todros, I. Concina, G. Faglia, M. Ferroni, G. Jimenez, A.
Ponzoni, A. Vomiero and G. Sberveglieri |
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CNR-IDASC SENSOR Lab & University of Brescia, BRESCIA , Italy |
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Nanowires
of semiconducting metal-oxide are investigated in order to produce a
novel class of sensing devices. These fascinating nanostructures may be
produced in several unusual arrangements such as nanowires, nanorods,
or nanocombs, resulting in great potential for application. The
synthesis of quasi 1-dimensional nanostructures of Sn, Zn oxides is
based on the thermal decomposition of precursor powders followed by
vapor-solid (VS) or vapor-liquid-solid (VLS) process. Such a growth
occurs in controlled thermodynamic condition and is highly promising
for nanostructure fabrication, due to its flexibility and low cost with
respect to the technology of silicon processing and to other top-down
approaches. The electrical and optical properties of nanowires have
been investigated. The effect of reactive gases on the electrical
conductance of semiconducting metal-oxides nanowires is the basic
mechanism for the development of nanodevices with enhanced sensing
performance.
Photoluminescence spectroscopy was also performed for the purpose of
investigating the behavior of photoluminescence spectrum in presence of
reactive gases.
Applications of nanowires to third generation solar cells has also been
investigated.Excitonic solar cells (either dye- or quantum
dot-sensitized) are strong candidates for development in the field.
Among the very recent and most promising advances in excitonic cells,
integration of single crystal nanowires of transparent conducting
oxides in photoanodes has been considered. The beneficial effect of the
composite network of mixed nanocrystalline powders and single
crystalline nanowires will be analyzed and discussed from the viewpoint
of the functional features of the cells either dye- or quantum
dot-sensitized.
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